Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3-C4 Hydrocarbons

被引：5
|
作者：
Sobolev, Vladimir I. [1 ,2 ]
Koltunov, Konstantin Yu. [1 ,3 ]
Zenkovets, Galina A. [1 ,3 ]
机构：
[1] Russian Acad Sci, Boreskov Inst Catalysis, Pr Akad Lavrentieva 5, Novosibirsk 630090, Russia
[2] Tomsk State Univ, 36 Lenina Ave, Tomsk 634050, Russia
[3] Novosibirsk State Univ, Pirogova 2, Novosibirsk 630090, Russia
来源：
CATALYSIS LETTERS | 2017年 / 147卷 / 02期
关键词：
Oxidative dehydrogenation; Multicomponent bismuth molybdate; 1-Butene; 1,3-Butadiene; Concurrent reactions; OXIDE-BASED CATALYSTS; SELECTIVE OXIDATION; N-BUTENE; MOLYBDENUM OXIDE; NICKEL CONTENT; ISOMERIZATION; METHACROLEIN; RAFFINATE-3; REACTIVITY; KINETICS;
D O I：
10.1007/s10562-016-1947-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The influence of light hydrocarbons, such as n-butane, isobutane, propylene, cis- and trans-2-butenes, and isobutene on the oxidative dehydrogenation of 1-butene to 1,3-butadiene over BiMoKNiCoFePOx/SiO2 catalyst has been studied using a gas flow reactor. The inhibition effect of the listed hydrocarbons on the target reaction increased in the order of n-butane similar to isobutane < propylene < 2-butenes < isobutene. In addition, in contrast to 1-butene, isobutene has shown significant contribution to coke formation. It was suggested, that the coke formation and therefore the rate of the catalyst regeneration exercise a significant influence on the efficiency of 1-butene transformation into 1,3-butadiene in the concurrent presence of other hydrocarbons. [GRAPHICS] .
引用
收藏
页码：310 / 317
页数：8
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