Aryl-substituted sulfonium betaines: Preparation and use in the epoxidation of aldehydes

被引：11
作者：
Forbes, David C. [1 ]
Amin, Sejal R.
Bean, Christie J.
Standen, Michael C.
机构：
[1] Univ S Alabama, Dept Chem, Mobile, AL 36688 USA
[2] Synthetech, Albany, OR 97321 USA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 21期
关键词：
D O I：
10.1021/jo061370u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Thermally induced decarboxylation of carboxymethylsulfonium betaines results in formation of the corresponding sulfur ylides in situ. Decarboxylation rates for a range of arylcarboxymethylsulfonium betaine salts have been determined using NMR spectroscopy, and the efficiency of ylide generation and trapping has been evaluated via methylidene transfer to a range of aldehydes to form epoxides.
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页码：8287 / 8290
页数：4
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