Copper-catalyzed amination of aryl halides: single-step synthesis of triarylamines

被引:155
作者
Kelkar, AA [1 ]
Patil, NM [1 ]
Chaudhari, RV [1 ]
机构
[1] Natl Chem Lab, Homogeneous Catalysis Div, Pune 411008, Maharashtra, India
关键词
D O I
10.1016/S0040-4039(02)01708-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A simple and efficient methodology for the synthesis of triarylamines in a single step has been demonstrated using a ligand-free CuI catalyst and potassium tertiary butoxide as the base. Use of chelating ligands leads to the formation of triarylamine derivatives selectively (95% yield) with high catalytic activity. (C) 2002 Published by Elsevier Science Ltd.
引用
收藏
页码:7143 / 7146
页数:4
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