CAN mediated reaction of aryl sulfinates with alkenes and alkynes:: Synthesis of vinyl sulfones, β-iodovinyl sulfones and acetylenic sulfones

被引：80

作者：

Nair, V ^{[1
]}

Augustine, A ^{[1
]}

Suja, TD ^{[1
]}

机构：

[1] CSIR, Reg Res Lab, Div Organ Chem, Trivandrum 695019, Kerala, India

来源：

SYNTHESIS-STUTTGART | 2002年 / 15期

关键词：

cerium(IV) ammonium nitrate; sulfonylation; aryl alkenes; alkenes; acetylenes; vinyl sulfones; beta-iodovinyl sulfones; acetylenic sulfones;

D O I：

10.1055/s-2002-34838

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cerium(IV) ammonium nitrate (CAN) mediated reaction of aryl sulfinates and sodium iodide with alkenes afforded vinyl sulfones in very good yields. Alkynes underwent similar reaction to give beta-iodovinyl sulfones, which on treatment with potassium carbonate afforded the corresponding acetylenic sulfones in high yields.

引用

页码：2259 / 2265

页数：7

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