Active Edge Site Exposed β-Ni(OH)2 Nanosheets on Stainless Steel Mesh as a Versatile Electrocatalyst for the Oxidation of Urea, Hydrazine, and Water

被引:20
作者
Kashale, Anil A. [1 ]
Ghule, Anil, V [2 ]
Chen, I-Wen Peter [1 ]
机构
[1] Natl Taitung Univ, Dept Appl Sci, Taitung 95092, Taiwan
[2] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India
关键词
binder free; electrocatalyst; nanomaterials; Nickle; oxidation; LAYERED DOUBLE HYDROXIDE; ENERGY-CONVERSION; NICKEL-HYDROXIDE; ELECTROCHEMICAL DECOMPOSITION; HYDROGEN GENERATION; EVOLUTION REACTION; CATALYTIC-ACTIVITY; ALKALINE MEDIA; ELECTROOXIDATION; MECHANISM;
D O I
10.1002/cctc.202001528
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Energy generation through electrochemical conversion while addressing the environmental concerns has always been the topic of interest to the scientific community. Particularly, the development of low-cost and efficient electrocatalyst gained attention for large-scale energy and clean-energy production. But now the emphasis is on developing low-cost and efficient electrocatalyst materials that show more than one electrocatalytic reactions. Hence, we have developed a highly porous and active edge plane exposed beta-Ni(OH)(2) nanosheet on low-cost and flexible stainless-steel mesh (SSM) and investigated its catalytic activity for oxidation of urea, hydrazine, and water. The as-prepared beta-Ni(OH)(2)/SSM demonstrates the excellent catalytic activity towards the urea oxidation reaction (UOR), hydrazine oxidation reaction (HzOR), and oxygen evolution reaction (OER) with potential lower than the 1.45 V vs. RHE, 1.34 V vs. RHE, and 1.51 V vs. RHE at 50 mA/cm(2) current density, respectively. Furthermore, the as-prepared electrocatalyst demonstrates excellent stability in UOR, HzOR, and OER for long time. The promising electrocatalytic activity of as-prepared beta-Ni(OH)(2)/SSM electrocatalyst is attributed to the highly porous, and edge plane exposed binder-free thin nanosheets grown on SSM, which also adds to the mechanical structure stability and a large amount of mass transportation during electrocatalytic activity.
引用
收藏
页码:1165 / 1174
页数:10
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