Palladium catalyzed intramolecular hydrocarbonation of allenes leading to carbocycles

被引：60

作者：

Meguro, M ^{[1
]}

Kamijo, S ^{[1
]}

Yamamoto, Y ^{[1
]}

机构：

[1] TOHOKU UNIV,GRAD SCH SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 41期

关键词：

D O I：

10.1016/0040-4039(96)01609-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intramolecular hydrocarbonation of certain allenes (1 and 3), bearing active methyne groups al the terminus of the carbon chain, proceeded smoothly in the presence of catalytic amounts of palladium complex ([(eta(3)-C3H5)PdCl](2)-dppf) to give the corresponding carbocycles (2 and 4, respectively) in good to high yields. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：7453 / 7456

页数：4

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