Kinetics of zinc ions removal from effluents using ion exchange resin

被引:90
作者
Shek, Tsz-Him [1 ]
Ma, Anthony [1 ]
Lee, Vinci K. C. [1 ]
McKay, Gordon [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Chem Engn, Kowloon, Hong Kong, Peoples R China
关键词
Ion exchange; Resin; Zinc; Removal; Isotherm; Kinetics; AQUEOUS-SOLUTIONS; METAL-IONS; BONE CHAR; ACTIVATED CARBON; SORPTION; ADSORPTION; BIOSORPTION; CADMIUM; ZN(II); COPPER;
D O I
10.1016/j.cej.2008.05.019
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The ability of anew ion exchange resin to remove zinc ions from effluent has been studied. The equilibrium exchange capacity has been de;ermined as 2.7 mmol/g resin and analysed using the Langmuir, Freundlich and Redlich-Peterson equations. The Redlich-Peterson gave the best-fit to the experimental data. A series of kinetic studies were carried out in an agitated batch reactor. Three variables were studied, initial zinc ion concentration. resin mass and resin particle size. The results were analysed using three kinetic models, pseudo-first order, pseudo-second order and the Elovich model. The results were compared on the basis of SSE values and the best-fit correlation of the experimental data was obtained using the Elovich model which suggests a chemisorption process. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:63 / 70
页数:8
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