Study of the Structural and Electrical Behaviour of Ca Doped LaInO3 Electrolyte Material

被引：12

作者：

Sood, Kapil ^{[1
]}

Singh, K. ^{[1
]}

Pandey, O. P. ^{[1
]}

机构：

[1] Thapar Univ, Sch Phys & Mat Sci, Patiala, Punjab, India

来源：

TRANSACTIONS OF THE INDIAN CERAMIC SOCIETY | 2013年 / 72卷 / 01期

关键词：

XRD; Electrolyte; Perovskite; Ionic conductivity; CONDUCTIVITY; OXIDE;

D O I：

10.1080/0371750X.2013.795728

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

LaInO3 has been doped with CaO to study the structural changes that lead to variation in properties of the electrolyte. It has been observed that LaInO3 is orthorhombic in nature, but with addition of Ca above certain value, it gets distorted from its orthorhombic symmetry. The electrical conductivity of the material has also been studied. The ac impedance plots have been used to analyze the electrical properties of the doped sample. The plots clearly indicate that the replacement of La by Ca enhances ionic conductivity of the system, whereas substitution of Ca at In site is rather difficult due to large difference in the ionic radii. The conductivity observed is of the order of 10(-4) S.cm(-1) at 800 degrees C for 10 mol% doped Ca in LaInO3.

引用

页码：32 / 35

页数：4

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