Aryl-aryl bond formation by transition-metal-catalyzed direct arylation

被引：3411
作者：
Alberico, Dino [1 ]
Scott, Mark E. [1 ]
Lautens, Mark [1 ]
机构：
[1] Univ Toronto, Dept Chem, Davenport Labs, Toronto, ON M5S 3H6, Canada
来源：
CHEMICAL REVIEWS | 2007年 / 107卷 / 01期
关键词：
D O I：
10.1021/cr0509760
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review covers the development and advances in transition-metal-catalyzed aryl-aryl bond formation by direct arylation as well as its application to the synthesis of important compounds including natural products, pharmaceuticals, catalyst ligands and materials. Studies focused on developing milder, lower temperature direct arylation reactions are discussed in addition to recent studies that focused on the fine-tuning of catalyst systems to allow for the use of more inexpensive and industrially attractive aryl chlorides. It is emphasized that these studies will help both synthetic and material chemicals a great deal, making direct arylation a valuable tool for diverse academic and industrial applications.
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页码：174 / 238
页数：65
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