Catalyst surfaces with tunable hydrophilicity and hydrophobicity: metal-organic frameworks toward controllable catalytic selectivity

被引:48
作者
Chen, Xinyi
Qian, Panpan
Zhang, Tao
Xu, Zhiling
Fang, Chuanzhen
Xu, Xiujie
Chen, Wanzheng
Wu, Peng
Shen, Yu
Li, Sheng
Wu, Jiansheng
Zheng, Bing
Zhang, Weina
Huo, Fengwei [1 ]
机构
[1] Nanjing Tech Univ NanjingTech, Key Lab Flexible Elect KLOFE, 30 South Puzhu Rd, Nanjing 211816, Jiangsu, Peoples R China
基金
美国国家科学基金会; 国家重点研发计划;
关键词
GRAPHENE OXIDE; OXIDATION; WATER; WETTABILITY; STABILITY; FACILE; HYDROGENATION; ENCAPSULATION; PERFORMANCE; CHEMISTRY;
D O I
10.1039/c8cc00318a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This report describes a facile strategy that has the capability of adjusting different surface hydrophilicities/hydrophobicities of catalysts by covering metal-organic frameworks with graphene oxide and reduced graphene oxide. The catalysts exhibit remarkable catalytic selective performance for the hydrogenation of different hydrophobic and hydrophilic reactants.
引用
收藏
页码:3936 / 3939
页数:4
相关论文
共 46 条
[11]   A new breakthrough in selective catalysis: metal-organic framework nanocomposites with sandwich structure [J].
Huo, Fengwei .
SCIENCE BULLETIN, 2016, 61 (22) :1726-1727
[12]   Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal-Organic Frameworks [J].
Jiang, Hai-Long ;
Feng, Dawei ;
Liu, Tian-Fu ;
Li, Jian-Rong ;
Zhou, Hong-Cai .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (36) :14690-14693
[13]   Porous metal-organic frameworks as platforms for functional applications [J].
Jiang, Hai-Long ;
Xu, Qiang .
CHEMICAL COMMUNICATIONS, 2011, 47 (12) :3351-3370
[14]   Heteroaggregation behavior of graphene oxide on Zr-based metal-organic frameworks in aqueous solutions: a combined experimental and theoretical study [J].
Li, Jie ;
Wu, Qunyan ;
Wang, Xiangxue ;
Chai, Zhifang ;
Shi, Weiqun ;
Hou, Jing ;
Hayat, Tasawar ;
Alsaedi, Ahmed ;
Wang, Xiangke .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (38) :20398-20406
[15]   Boosting selective oxidation of cyclohexane over a metal-organic framework by hydrophobicity engineering of pore walls [J].
Li, Luyan ;
Yang, Qihao ;
Chen, Si ;
Hou, Xudong ;
Liu, Bo ;
Lu, Junling ;
Jiang, Hai-Long .
CHEMICAL COMMUNICATIONS, 2017, 53 (72) :10026-10029
[16]   Enhancing Water Oxidation Catalysis on a Synergistic Phosphorylated NiFe Hydroxide by Adjusting Catalyst Wettability [J].
Li, Yibing ;
Zhao, Chuan .
ACS CATALYSIS, 2017, 7 (04) :2535-2541
[17]   Heterogeneous Catalysis in Zeolites, Mesoporous Silica, and Metal-Organic Frameworks [J].
Liang, Jie ;
Liang, Zibin ;
Zou, Ruqiang ;
Zhao, Yanli .
ADVANCED MATERIALS, 2017, 29 (30)
[18]   Wettability-Driven Palladium Catalysis for Enhanced Dehydrogenative Coupling of Organosilanes [J].
Lin, Jian-Dong ;
Bi, Qing-Yuan ;
Tao, Lei ;
Jiang, Tao ;
Liu, Yong-Mei ;
He, He-Yong ;
Cao, Yong ;
Wang, Yang-Dong .
ACS CATALYSIS, 2017, 7 (03) :1720-1727
[19]   Methanol synthesis in a three-phase catalytic bed under nonwetted condition [J].
Ling, Dan ;
Liu, Peng ;
Cheng, Zhen-Min .
AICHE JOURNAL, 2017, 63 (01) :226-237
[20]   Designable Yolk-Shell Nanoparticle@MOF Petalous Heterostructures [J].
Liu, Yayuan ;
Zhang, Weina ;
Li, Shaozhou ;
Cui, Chenlong ;
Wu, Jin ;
Chen, Hongyu ;
Huo, Fengwei .
CHEMISTRY OF MATERIALS, 2014, 26 (02) :1119-1125