Synthesis, photochemical and photophysical properties of novel unsymmetrically substituted zinc(II) phthalocyanines

被引：15

作者：

Al-Raqa, Shaya Y. ^{[1
]}

机构：

[1] Taibah Univ, Fac Sci, Dept Chem, Al Madinah Al Munawrah, Saudi Arabia

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2006年 / 10卷 / 01期

关键词：

Suzuki coupling; singlet oxygen; photooxidation; phthalocyanine;

D O I：

10.1142/S1088424606000077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of three novel unsymmetrical free base. zinc(II) phthalocyanine derivatives obtained from 3,6-di-(thiophen-3-yl)phthalonitrile and 3,6-didecylphilialonitile are described. The synthesis of novel 3,6-substituted plithalonitriles bearing heteroaromatic derivatives were achieved through Suzuki-coupling reaction by treatment of 3.6-di(trifluoromethanesulfonyloxy)phthalonitriles and heteroaromatic boronic acids. Two of the newly synthesized complexes showed a high efficiency against a model biological Substrate, such as N-acetyl-L-tryptophanamide NATA, and shows a high sin-let oxygen quantum yield. Copyright (c) 2006 Society of Porphyrins & Phthalocyanines.

引用

页码：55 / 62

页数：8

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