The influences of reduction temperature on the initial performance and short time durability of nickel-yttria-stabilized zirconia, composite solid oxide fuel cell anode were investigated. Anode microstructures before and after operation were quantitatively analyzed by three-dimensional reconstruction based on focused ion beam -scanning electron microscopy technique. The anode reduced at 500 degrees C showed the worst initial performance and stability in operation and the anode reduced at 800 degrees C showed the smallest polarization resistance. The anode reduced at 1000 degrees C showed the most stable performance with polarization resistance enhanced with operation. It is found that higher reduction temperature leads to dense nickel and enhances nickelyttria-stabilized-zirconia interfacial bonding, which can inhibit nickel sintering and improve the composite anode stability in long-time operation.
机构:
Ecole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, SwitzerlandEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Jeangros, Q.
;
Hansen, T. W.
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Tech Univ Denmark, Ctr Electron Nanoscopy, DK-2800 Lyngby, DenmarkEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Hansen, T. W.
;
Wagner, J. B.
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Tech Univ Denmark, Ctr Electron Nanoscopy, DK-2800 Lyngby, DenmarkEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Wagner, J. B.
;
Damsgaard, C. D.
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Tech Univ Denmark, Ctr Electron Nanoscopy, DK-2800 Lyngby, DenmarkEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Damsgaard, C. D.
;
Dunin-Borkowski, R. E.
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Julich Res Ctr, Ernst Ruska Ctr Microscopy & Spect Electrons, Julich, Germany
Julich Res Ctr, Peter Grunberg Inst, Julich, GermanyEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Dunin-Borkowski, R. E.
;
Hebert, C.
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Ecole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, SwitzerlandEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Hebert, C.
;
Van Herle, J.
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Ecole Polytech Fed Lausanne, Ind Energy Syst Lab, Lausanne, SwitzerlandEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Van Herle, J.
;
Hessler-Wyser, A.
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Ecole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, SwitzerlandEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
机构:
Ecole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, SwitzerlandEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Jeangros, Q.
;
Hansen, T. W.
论文数: 0引用数: 0
h-index: 0
机构:
Tech Univ Denmark, Ctr Electron Nanoscopy, DK-2800 Lyngby, DenmarkEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Hansen, T. W.
;
Wagner, J. B.
论文数: 0引用数: 0
h-index: 0
机构:
Tech Univ Denmark, Ctr Electron Nanoscopy, DK-2800 Lyngby, DenmarkEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Wagner, J. B.
;
Damsgaard, C. D.
论文数: 0引用数: 0
h-index: 0
机构:
Tech Univ Denmark, Ctr Electron Nanoscopy, DK-2800 Lyngby, DenmarkEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Damsgaard, C. D.
;
Dunin-Borkowski, R. E.
论文数: 0引用数: 0
h-index: 0
机构:
Julich Res Ctr, Ernst Ruska Ctr Microscopy & Spect Electrons, Julich, Germany
Julich Res Ctr, Peter Grunberg Inst, Julich, GermanyEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Dunin-Borkowski, R. E.
;
Hebert, C.
论文数: 0引用数: 0
h-index: 0
机构:
Ecole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, SwitzerlandEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Hebert, C.
;
Van Herle, J.
论文数: 0引用数: 0
h-index: 0
机构:
Ecole Polytech Fed Lausanne, Ind Energy Syst Lab, Lausanne, SwitzerlandEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland
Van Herle, J.
;
Hessler-Wyser, A.
论文数: 0引用数: 0
h-index: 0
机构:
Ecole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, SwitzerlandEcole Polytech Fed Lausanne, Interdisciplinary Ctr Electron Microscopy, Lausanne, Switzerland