Two Mn2IILn4III (Ln = Gd, Eu) hexanuclear compounds of p-tert-butylsulfinylcalix[4]arene

被引：52

作者：

Bi, Yanfeng ^{[1
,3
]}

Wang, Xiu-Teng ^{[2
]}

Wang, Bing-Wu ^{[2
]}

Liao, Wuping ^{[1
]}

Wang, Xiaofei ^{[1
,3
]}

Zhang, Hongjie ^{[1
]}

Gao, Song ^{[2
]}

Li, Deqian ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

DALTON TRANSACTIONS | 2009年 / 12期

基金：

中国国家自然科学基金;

关键词：

MAGNETIC-PROPERTIES; TRANSITION-METAL; MOLECULAR-STRUCTURE; SPIN CLUSTERS; COMPLEXES; LANTHANIDE; CRYSTAL; IONS; TETRANUCLEAR; 3D;

D O I：

10.1039/b817515b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two 3d-4f heterometallic compounds of p-tert-butylsulfinylcalix[4] arene were synthesized by the solvothermal method and characterized by some hinged double-dumbbell-like subunits in which two perpendicular dumbbell entities were constructed by an in-between isosceles triangle Mn(II)Ln(2)(III), and two tail-to-tail calixarene molecules, and hinged by the lanthanide-sulfinyl group bonding. The magnetic properties of the title compounds were examined.

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页码：2250 / 2254

页数：5

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