Effect of particle size on the UV absorbance of zinc oxide nanoparticles

被引:195
作者
Goh, E. G. [1 ]
Xu, X. [1 ]
McCormick, P. G. [1 ]
机构
[1] Univ Western Australia, Sch Mech & Chem Engn, Nedlands, WA 6009, Australia
关键词
Nanostructured materials; Zinc oxide; Modeling; Simulation; UV absorbance; ZNO QUANTUM DOTS;
D O I
10.1016/j.scriptamat.2014.01.033
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effect of particle size on the UV absorption of zinc oxide nanoparticles has been investigated in the size range above the quantum limit. The results show that the absorbance increases with increasing size for particle sizes of 15-40 nm. The results are evaluated in terms of intrinsic particle absorption and the number concentration of particles. It is shown that the particles become opaque for particle sizes greater than 70 nm. For larger sizes the absorbance decreases with increasing size due to the decrease in particle concentration. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:49 / 52
页数:4
相关论文
共 12 条
  • [1] PREPARATION AND CHARACTERIZATION OF QUANTUM SIZE ZINC-OXIDE - A DETAILED SPECTROSCOPIC STUDY
    BAHNEMANN, DW
    KORMANN, C
    HOFFMANN, MR
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (14) : 3789 - 3798
  • [2] Band gap variation of size-controlled ZnO quantum dots synthesized by sol-gel method
    Lin, KF
    Cheng, HM
    Hsu, HC
    Lin, LJ
    Hsieh, WF
    [J]. CHEMICAL PHYSICS LETTERS, 2005, 409 (4-6) : 208 - 211
  • [3] Rapid synthesis of stable ZnO quantum dots
    Mädler, L
    Stark, WJ
    Pratsinis, SE
    [J]. JOURNAL OF APPLIED PHYSICS, 2002, 92 (11) : 6537 - 6540
  • [4] Synthesis and growth of ZnO nanoparticles
    Meulenkamp, EA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (29) : 5566 - 5572
  • [5] Palmer B.R., 2000, J COATING TECHNOL, V62, P789
  • [6] Effect of particle size on the reactivity of quantum size ZnO nanoparticles and charge-transfer dynamics with adsorbed catechols
    Ramakrishna, G
    Ghosh, HN
    [J]. LANGMUIR, 2003, 19 (07) : 3006 - 3012
  • [7] Analysis of Optical Absorbance Spectra for the Determination of ZnO Nanoparticle Size Distribution, Solubility, and Surface Energy
    Segets, Doris
    Gradl, Johannes
    Taylor, Robin Klupp
    Vassilev, Vassil
    Peukert, Wolfgang
    [J]. ACS NANO, 2009, 3 (07) : 1703 - 1710
  • [8] Optical characterization of ZnO nanoparticles capped with various surfactants
    Singla, M. L.
    Shafeeq, Muhamed M.
    Kumar, Manish
    [J]. JOURNAL OF LUMINESCENCE, 2009, 129 (05) : 434 - 438
  • [9] OPTICAL PROPERTIES AND ELECTRONIC STRUCTURE OF AMORPHOUS GERMANIUM
    TAUC, J
    GRIGOROVICI, R
    VANCU, A
    [J]. PHYSICA STATUS SOLIDI, 1966, 15 (02): : 627 - +
  • [10] ZnO nanoparticles synthesised by mechanochemical processing
    Tsuzuki, T
    McCormick, PG
    [J]. SCRIPTA MATERIALIA, 2001, 44 (8-9) : 1731 - 1734