catena-poly[bis{N-(2-pyridylmethyl)imidazole-κN}(μ-sulfato-κ2O,O′) diaquacobalt(II)]

被引：2

作者：

Lou, Tian-Jun ^{[1
]}

Li, Yong-Fang ^{[1
]}

Zhu, Yong ^{[1
]}

机构：

[1] Henan Inst Sci & Technol, Coll Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷

关键词：

COORDINATION POLYMERS; CHEMISTRY; SQUARE; LIGAND;

D O I：

10.1107/S1600536806040050

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Co(C9H9N3)(2)(H2O)(2)(SO4)](n), is a one-dimensional coordination polymer formed by sulfate bridges between the Co-II atoms. The Co-II and sulfate S atoms lie on an inversion centre and a twofold rotation axis, respectively. The Co-II atom is coordinated in a slightly deformed octahedral geometry by two O atoms of the sulfate anions, two water molecules and two imidazole N atoms from the N-(2-pyridylmethyl) imidazole ligands, with the pyridyl groups uncoordinated.

引用

页码：M2832 / M2834

页数：3

共 12 条

[1] *BRUK AXS INC, 1998, SAINT SMART
[2] Synthesis, structural characterization, computational study, and catalytic activity of metal complexes based on tetradentate pyridine/N-heterocyclic carbene ligand
Chiu, PL
Lai, CL
Chang, CF
Hu, CH
Lee, HM
[J]. ORGANOMETALLICS, 2005, 24 (25) : 6169 - 6178
[3] Synthesis and characterization of new coordination polymers generated from oxadiazole-containing ligand and inorganic M(II) [M = Cu(II), Co(II)] salts
Dong, YB
Ma, JP
Huang, RQ
Liang, FZ
Smith, MD
[J]. DALTON TRANSACTIONS, 2003, (08) : 1472 - 1479
[4] Syntheses, structures, and magnetic properties of three novel metal-malate-bipyridine coordination polymers with layered and pillared topology
Duan, LM
Xie, FT
Chen, XY
Chen, Y
Lu, YK
Cheng, P
Xu, JQ
[J]. CRYSTAL GROWTH & DESIGN, 2006, 6 (05) : 1101 - 1106
[5] One-dimensional coordination polymers of cobalt with 4,4′-bipyridine:: Syntheses and structures
Lu, J
Yu, C
Niu, TY
Paliwala, T
Crisci, G
Somosa, F
Jacobson, AJ
[J]. INORGANIC CHEMISTRY, 1998, 37 (18) : 4637 - 4640
[6] Three supramolecular isomers of square grid networks from the assembly of a flexible spacer and Co(NCS)2:: Structures and polymer transformation
Peng, YF
Ge, HY
Li, BZ
Li, BL
Zhang, Y
[J]. CRYSTAL GROWTH & DESIGN, 2006, 6 (04) : 994 - 998
[7] Sheldrick G.M., 1997, SHELXS-97, a Program for the Automatic Solution of Crystal Structures
[8] Sheldrick G.M., 1996, SADABS
[9] SHELDRICK GM, 1997, SHELXTL VERSION 5 10
[10] COORDINATION CHEMISTRY OF IMIDAZOLE DERIVATIVES - SEARCH FOR CARBON-BOUND CHELATES WITH 1ST-ROW TRANSITION-METAL IONS
SUNDBERG, RJ
YILMAZ, I
MENTE, DC
[J]. INORGANIC CHEMISTRY, 1977, 16 (06) : 1470 - 1476

← 1 2 →