Thermal Expansion Behavior of Antiplasticized Polycarbonate

被引：17

作者：

Miyagawa, Azusa ^{[1
]}

Nobukawa, Shogo ^{[1
]}

Yamaguchi, Masayuki ^{[1
]}

机构：

[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan

来源：

NIHON REOROJI GAKKAISHI | 2014年 / 42卷 / 04期

关键词：

Polycarbonate; Antiplasticization; Mechanical properties; Viscoelastic properties; Thermal expansion; CELLULOSE-ACETATE PROPIONATE; FREE-VOLUME; POLY(METHYL METHACRYLATE); WAVELENGTH DISPERSION; GAMMA-RELAXATION; PLASTICIZATION; BIREFRINGENCE; BLENDS; FILMS; LIFETIME;

D O I：

10.1678/rheology.42.255

中图分类号：

O3 [力学];

学科分类号：

08 ; 0801 ;

摘要：

Thermal expansion behavior and viscoelastic properties of antiplasticized polycarbonate (PC) are studied employing p-terphenyl (p-tPh) as an antiplasticizer. The rheological characterization reveals that the free volume fraction at the glass transition temperature and thermal expansion coefficient of the free volume in the rubbery region are unchanged by the p-tPh addition. However, the linear coefficient of thermal expansion in the glassy region is found to be reduced, which can be attributed to the reduction of free volume in the glassy state. Since the antiplasticized PC exhibits high modulus with a low thermal expansion coefficient, its suitability as a replacement for inorganic glasses will be considered.

引用

页码：255 / 260

页数：6

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