A Triarylphosphine Ligand Bearing Dodeca(ethylene glycol) Chains: Enhanced Efficiency in the Palladium-Catalyzed Suzuki-Miyaura Coupling Reaction

被引：68

作者：

Fujihara, Tetsuaki ^{[1
]}

Yoshida, Shohei ^{[1
]}

Terao, Jun ^{[1
]}

Tsuji, Yasushi ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Kyoto 6158510, Japan

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 10期

关键词：

GEOMETRY OPTIMIZATION; ARYL CHLORIDES; DIELS-ALDER; WATER; PHOSPHINE; POLYETHYLENEGLYCOL; PHASE; CROSS;

D O I：

10.1021/ol900578g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new phosphine bearing dodeca(ethylene glycol) chains has been synthesized and employed as a ligand in the palladium-catalyzed Suzuki-Miyaura coupling reaction. The system was found to be highly effective using unactivated aryl chlorides as the substrate.

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页码：2121 / 2124

页数：4

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