Electrocatalytic Hydrogenation of Biomass-Derived Organics: A Review

被引：256

作者：

Akhade, Sneha A. ^{[1
,2
]}

Singh, Nirala ^{[1
,3
]}

Gutierrez, Oliver Y. ^{[1
]}

Lopez-Ruiz, Juan ^{[1
]}

Wang, Huamin ^{[1
]}

Holladay, Jamie D. ^{[4
,5
]}

Liu, Yue ^{[4
,5
]}

Karkamkar, Abhijeet ^{[1
]}

Weber, Robert S. ^{[1
]}

Padmaperuma, Asanga B. ^{[1
]}

Lee, Mal-Soon ^{[1
]}

Whyatt, Greg A. ^{[1
]}

Elliott, Michael ^{[1
]}

Holladay, Johnathan E. ^{[1
]}

Male, Jonathan L. ^{[1
]}

Lercher, Johannes A. ^{[1
]}

Rousseau, Roger ^{[1
]}

Glezakou, Vassiliki-Alexandra ^{[1
]}

机构：

[1] Pacific Northwest Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA

[2] Lawrence Livermore Natl Lab, Mat Sci Div, Livermore, CA 94550 USA

[3] Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA

[4] Tech Univ Munich, Dept Chem, D-84747 Garching, Germany

[5] Tech Univ Munich, Catalysis Res Ctr, D-84747 Garching, Germany

来源：

CHEMICAL REVIEWS | 2020年 / 120卷 / 20期

关键词：

BOND-CLEAVAGE REACTIONS; FAST PYROLYSIS OIL; POLYMER ELECTROLYTE REACTOR; RANEY-NICKEL ELECTRODE; REAL SURFACE-AREA; X-RAY-ABSORPTION; ELECTROCHEMICAL REDUCTION; LEVULINIC ACID; OXALIC-ACID; WASTE-WATER;

D O I：

10.1021/acs.chemrev.0c00158

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sustainable energy generation calls for a shift away from centralized, high-temperature, energy-intensive processes to decentralized, low-temperature conversions that can be powered by electricity produced from renewable sources. Electrocatalytic conversion of biomass-derived feedstocks would allow carbon recycling of distributed, energy-poor resources in the absence of sinks and sources of high-grade heat. Selective, efficient electrocatalysts that operate at low temperatures are needed for electrocatalytic hydrogenation (ECH) to upgrade the feedstocks. For effective generation of energy-dense chemicals and fuels, two design criteria must be met: (i) a high H:C ratio via ECH to allow for high-quality fuels and blends and (ii) a lower O:C ratio in the target molecules via electrochemical decarboxylation/deoxygenation to improve the stability of fuels and chemicals. The goal of this review is to determine whether the following questions have been sufficiently answered in the open literature, and if not, what additional information is required: (1) What organic functionalities are accessible for electrocatalytic hydrogenation under a set of reaction conditions? How do substitutions and functionalities impact the activity and selectivity of ECH? (2) What material properties cause an electrocatalyst to be active for ECH? Can general trends in ECH be formulated based on the type of electrocatalyst? (3) What are the impacts of reaction conditions (electrolyte concentration, pH, operating potential) and reactor types?

引用

页码：11370 / 11419

页数：50

共 370 条

[1] Waste to bioproduct conversion with undefined mixed cultures: the carboxylate platform [J].

Agler, Matthew T. ;

Wrenn, Brian A. ;

Zinder, Stephen H. ;

Angenent, Largus T. .

TRENDS IN BIOTECHNOLOGY, 2011, 29 (02) :70-78

[2] Distributed energy resources and benefits to the environment [J].

Akorede, Mudathir Funsho ;

Hizam, Hashim ;

Pouresmaeil, Edris .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2010, 14 (02) :724-734

[3] DIFFUSION COEFFICIENTS OF CARBOXYLIC ACIDS [J].

ALBERY, WJ ;

GREENWOOD, AR ;

KIBBLE, RF .

TRANSACTIONS OF THE FARADAY SOCIETY, 1967, 63 (530P) :360-+

[4] ELECTROCATALYTIC HYDROGENATION OF PHENOL ON HIGHLY DISPERSED PT ELECTRODES [J].

AMOUZEGAR, K ;

SAVADOGO, O .

ELECTROCHIMICA ACTA, 1994, 39 (04) :557-559

[5] Electrocatalytic hydrogenation of phenol on dispersed Pt: Effect of metal electrochemically active surface area and electrode material [J].

Amouzegar, K ;

Savadogo, O .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1997, 27 (05) :539-542

[6] Electrocatalytic hydrogenation of phenol on dispersed Pt: reaction mechanism and support effect [J].

Amouzegar, K ;

Savadogo, O .

ELECTROCHIMICA ACTA, 1998, 43 (5-6) :503-508

[7] Current efficiency for soybean oil hydrogenation in a solid polymer electrolyte reactor [J].

An, W ;

Hong, JK ;

Pintauro, PN .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1998, 28 (09) :947-954

[8] The electrochemical hydrogenation of edible oils in a solid polymer electrolyte reactor. I. Reactor design and operation [J].

An, WD ;

Hong, JK ;

Pintauro, PN ;

Warner, K ;

Neff, W .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1998, 75 (08) :917-925

[9] THE ELECTROCATALYTIC HYDROGENATION OF GLUCOSE .1. KINETICS OF HYDROGEN EVOLUTION AND GLUCOSE HYDROGENATION ON RANEY-NICKEL POWDER [J].

ANANTHARAMAN, V .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (10) :2729-2741

[10] Electrocatalytic biomass conversion into petrochemicals. Review [J].

Andreev, V. N. ;

Grinberg, V. A. ;

Dedov, A. G. ;

Loktev, A. S. ;

Moiseev, I. I. ;

Tsivadze, A. Yu. .

PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2013, 49 (01) :32-39

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