A Single-Chain Magnet with a Very High Blocking Temperature and a Strong Coercive Field

被引：64

作者：

Allao Cassaro, Rafael A. ^{[1
]}

Reis, Samira G. ^{[2
]}

Araujo, Thamyres S. ^{[2
]}

Lahti, Paul M. ^{[3
]}

Novak, Miguel A. ^{[4
]}

Vaz, Maria G. F. ^{[2
]}

机构：

[1] Univ Fed Rio de Janeiro, Inst Quim, BR-21941909 Rio De Janeiro, Brazil

[2] Univ Fed Fluminense, Inst Quim, BR-24020150 Rio De Janeiro, Brazil

[3] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

[4] Univ Fed Rio de Janeiro, Inst Fis, BR-21941972 Rio De Janeiro, Brazil

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 19期

关键词：

SITE ANISOTROPY; NANOWIRES; COMPLEXES; EXCHANGE; MN;

D O I：

10.1021/acs.inorgchem.5b01431

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two isostructural ID complexes, [M(hfac)(2)NaphNN](n) [M = Mn-II (1) or Co-II (2); NaphNN = 1-naphthyl nitronylnitroxide], were synthesized and exhibit very strong antiferromagnetic metal radical exchange coupling. Compound 2 shows slow magnetic relaxation behavior with a high blocking temperature (T-B approximate to 13.2 K) and a very high coercive field of 49 kOe at 4.0 K.

引用

页码：9381 / 9383

页数：3

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