Measurement and correlation of vapor-liquid equilibria for the ethanol plus n-heptane system near the critical region

被引：22
|
作者：
Seo, J
Lee, S
Kim, H
机构：
[1] Seoul Natl Univ, Sch Chem Engn, Gwanak Gu, Seoul 151744, South Korea
[2] Seoul Natl Univ, Inst Chem Proc, Gwanak Gu, Seoul 151744, South Korea
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2002年 / 47卷 / 04期
关键词：
D O I：
10.1021/je0200057
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Isothermal VLE data for ethanol 4- n-heptane have been obtained at near-critical temperatures. The critical pressures determined from the critical opalescence of the mixtures were compared with published work for ethanol + n-butane, ethanol + n-pentane, and ethanol + n-hexane systems. A circulating type apparatus with a view cell has been used. These mixtures are highly nonideal because of the association of ethanol, and the data could be correlated with sufficient accuracy by using the Peng-Robinson-Stryjek-Vera (PRSV) equation of state with Wong-Sandler mixing rules.
引用
收藏
页码：974 / 977
页数：4
相关论文
共 50 条
  • [21] 3-PHASE LIQUID LIQUID VAPOR EQUILIBRIA IN THE NITROGEN + METHANE + N-HEPTANE SYSTEM
    CHEN, WL
    LUKS, KD
    KOHN, JP
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (03): : 312 - 314
  • [22] Measurement and Correlation of Vapor-Liquid Equilibria for ETBE plus Ethanol, ETBE plus Octane, Ethanol plus Octane and ETBE plus Ethanol plus Octane Systems at Atmospheric Pressure
    Watanabe, Tohru
    Yonezawa, Setsuko
    Kobuchi, Shigetoshi
    Honda, Katsumi
    Arai, Yasuhiko
    KAGAKU KOGAKU RONBUNSHU, 2010, 36 (02) : 75 - 79
  • [23] Vapor-liquid equilibria for pentane plus dodecane and heptane plus dodecane at low pressures
    de Oliveira, HNM
    Lopes, FWB
    Neto, AAD
    Chiavone, O
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2002, 47 (06): : 1384 - 1387
  • [24] Measurement and Correlation of Vapor-Liquid Equilibria for Hexamethyl Disiloxane plus Vinyl Acetate System at 101.3 kPa
    Zhang Wenlin
    Du Wei
    Meng Nan
    Sun Ruyi
    Li Chunli
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2014, 22 (02) : 177 - 180
  • [25] Investigation on Isobaric Vapor-Liquid Equilibria of the Isopropyl Acetate plus Water plus Ethanol System
    Li, Geng
    Yin, Xianqing
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2018, 63 (06): : 2009 - 2014
  • [26] Vapor-liquid equilibria of methanol + hexane, methanol + heptane, ethanol + hexane, ethanol + heptane, and ethanol + octane at 298.15 K
    Hongo, Masaru, 1600, ACS, Washington, DC, United States (39):
  • [27] Liquid-Liquid Equilibria of Benzene plus n-Heptane plus N,N-Dimethylformamide and Benzene plus n-Heptane plus N,N-Dimethylformamide plus Ammonium Thiocyanate
    Yang, Xiaoguang
    Song, Qilong
    Dong, Hongxing
    Li, Yongrui
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2014, 59 (01): : 22 - 27
  • [28] Measurement and prediction of solid-liquid phase equilibria for diamine plus n-heptane, or cyclohexane
    Allal, F
    Dahmani, A
    FLUID PHASE EQUILIBRIA, 2001, 190 (1-2) : 33 - 45
  • [29] Vapor-liquid equilibria for N-methyl-2-pyrrolidone plus benzene, plus toluene, plus heptane, and plus methylcyclohexane
    Linek, J
    Wichterle, I
    Marsh, KN
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (06): : 1212 - 1218
  • [30] LIQUID-LIQUID EQUILIBRIA FOR ANILINE PLUS BENZENE PLUS N-HEPTANE AND METHANOL PLUS ANILINE PLUS N-HEPTANE PLUS BENZENE AT 25-DEGREES-C
    NAGATA, I
    THERMOCHIMICA ACTA, 1994, 236 : 31 - 37
12345