Nanofiltration Membranes Based on Blend of Polysulfone-g-poly(tert-butylacrylate) Copolymer and Polysulfone

被引:3
作者
Mahdavi, Hossein [1 ]
Mahmoudian, Mehdi [1 ]
Shikhhasani, Farid [1 ]
机构
[1] Univ Tehran, Coll Sci, Sch Chem, Tehran, Iran
关键词
ULTRAFILTRATION MEMBRANES; SURFACE MODIFICATION; POLYETHERSULFONE MEMBRANES; HYDROPHILIC MODIFICATION; GRAFT-POLYMERIZATION;
D O I
10.1134/S1560090414040058
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nanofiltration membranes based on blend of polysulfone-g-poly(tert-butylacrylate) copolymer and polysulfone were prepared by phase inversion technique. ATRP grafting of tert-butylacrylate from chloromethylated polysulfone was used for the grafted polymer synthesis. The copolymer was characterized with FTIR, NMR, DSC and TGA. The prepared membranes were characterized in terms of pure water flux, water contact angle, cut off molecular weight, salt rejection and scanning electron microscopy.
引用
收藏
页码:494 / 503
页数:10
相关论文
共 31 条
[1]   Preparation and performance of polysulfone-sulfonated poly(ether ether ketone) blend ultrafiltration membranes. Part I [J].
Arthanareeswaran, G. ;
Mohan, D. ;
Raajenthiren, M. .
APPLIED SURFACE SCIENCE, 2007, 253 (21) :8705-8712
[2]   Synthesis of block copolymers for surface functionalization with stimuli-responsive macromolecules [J].
Berndt, Eva ;
Ulbricht, Mathias .
POLYMER, 2009, 50 (22) :5181-5191
[3]   Formation and morphology studies of different polysulfones-based membranes made by wet phase inversion process [J].
Blanco, Jean-Francois ;
Sublet, Julie ;
Nguyen, Quang Trong ;
Schaetzel, Pierre .
JOURNAL OF MEMBRANE SCIENCE, 2006, 283 (1-2) :27-37
[4]   Technical and economical evaluation of water recycling in the carwash industry with membrane processes [J].
Boussu, K. ;
Van Baelen, G. ;
Colen, W. ;
Eelen, D. ;
Vanassche, S. ;
Vandecasteele, C. ;
Van der Bruggen, B. .
WATER SCIENCE AND TECHNOLOGY, 2008, 57 (07) :1131-1135
[5]   Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].
Chiefari, J ;
Chong, YK ;
Ercole, F ;
Krstina, J ;
Jeffery, J ;
Le, TPT ;
Mayadunne, RTA ;
Meijs, GF ;
Moad, CL ;
Moad, G ;
Rizzardo, E ;
Thang, SH .
MACROMOLECULES, 1998, 31 (16) :5559-5562
[6]   Modi. cation of polysulfone membranes via surface-initiated atom transfer radical polymerization [J].
Dong, Han-Bang ;
Xu, You-Yi ;
Yi, Zhuan ;
Shi, Jun-Li .
APPLIED SURFACE SCIENCE, 2009, 255 (21) :8860-8866
[7]   SYNTHESIS AND CHARACTERIZATION OF CARBOXYLATED POLYSULFONES [J].
GUIVER, MD ;
CROTEAU, S ;
HAZLETT, JD ;
KUTOWY, O .
BRITISH POLYMER JOURNAL, 1990, 23 (1-2) :29-39
[8]   New polymer synthesis by nitroxide mediated living radical polymerizations [J].
Hawker, CJ ;
Bosman, AW ;
Harth, E .
CHEMICAL REVIEWS, 2001, 101 (12) :3661-3688
[9]   Preparation of polysulfone nanofiltration membranes by UV-assisted grafting polymerization for water softening [J].
Homayoonfal, Maryam ;
Akbari, Ahmad ;
Mehrnia, Mohammad Reza .
DESALINATION, 2010, 263 (1-3) :217-225
[10]   Metal-catalyzed living radical polymerization [J].
Kamigaito, M ;
Ando, T ;
Sawamoto, M .
CHEMICAL REVIEWS, 2001, 101 (12) :3689-3745