Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

被引：25

作者：

Fedushkin, Igor L. ^{[1
,2
]}

Sokolov, Vladimir G. ^{[1
,2
]}

Piskunov, Alexander V. ^{[1
,2
]}

Makarov, Valentine M. ^{[3
]}

Baranov, Eugeny V. ^{[1
,2
]}

Abakumov, Gleb A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia

[2] NI Lobachevskii Nizhny Novgorod State Univ, Nizhnii Novgorod 603950, Russia

[3] K Minin Nizhny Novgorod State Pedag Univ, Nizhnii Novgorod 603950, Russia

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 70期

基金：

俄罗斯科学基金会;

关键词：

CP-ASTERISK-GA; STRUCTURAL-CHARACTERIZATION; ELECTRON-TRANSFER; LIGAND; METAL; EPR; HETEROCYCLES; DIGALLANE;

D O I：

10.1039/c4cc04019h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A gallium(I) carbenoid derived from redox-active diimine 1,2-bis[(2,6-diisopropylphenyl) imino]acenaphthene (dpp-bian) in complexes with molybdenum may serve either as a neutral [(dpp-bian)Ga:] or an anionic [(dpp-bian)Ga:](-) two-electron donor depending on the electronic state of the transition metal.

引用

页码：10108 / 10111

页数：4