Non-Gaussian nature of glassy dynamics by cage to cage motion

被引:69
作者
Vorselaars, Bart
Lyulin, Alexey V.
Karatasos, K.
Michels, M. A. J.
机构
[1] Tech Univ Eindhoven, Eindhoven Polymer Labs, Grp Polymer Phys, NL-5600 MB Eindhoven, Netherlands
[2] Tech Univ Eindhoven, Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands
[3] Aristotle Univ Thessaloniki, Dept Chem Engn, Thessaloniki 54124, Greece
来源
PHYSICAL REVIEW E | 2007年 / 75卷 / 01期
关键词
D O I
10.1103/PhysRevE.75.011504
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
A model based on a single Brownian particle moving in a periodic effective field is used to understand the non-Gaussian dynamics in glassy systems of cage escape and subsequent recaging, often thought to be caused by a heterogeneous glass structure. The results are compared to molecular-dynamics simulations of systems with varying complexity: quasi-two-dimensional colloidlike particles, atactic polystyrene, and a dendritic glass. The model nicely describes generic features of all three topologically different systems, in particular around the maximum of the non-Gaussian parameter. This maximum is a measure for the average distance between cages.
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页数:6
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共 32 条
  • [1] [Anonymous], 1995, INTRO POLYM PHYS
  • [2] [Anonymous], 1995, RANDOM WALKS RANDOM, DOI [DOI 10.1079/PNS19950063, 10.1079/PNS19950063]
  • [3] Experimental evidence by neutron scattering of a crossover from Gaussian to non-Gaussian behavior in the α relaxation of polyisoprene -: art. no. 051802
    Arbe, A
    Colmenero, J
    Alvarez, F
    Monkenbusch, M
    Richter, D
    Farago, B
    Frick, B
    [J]. PHYSICAL REVIEW E, 2003, 67 (05): : 16
  • [4] NON-GAUSSIAN CORRECTIONS TO VAN HOVES GS(R,T) FOR A MONATOMIC GAS
    DESAI, RC
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (01) : 77 - +
  • [5] The origin of anomalous diffusion and non-Gaussian effects for hard spheres: analysis of three-time correlations
    Doliwa, B
    Heuer, A
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1999, 11 (10A) : A277 - A283
  • [6] Stringlike cooperative motion in a supercooled liquid
    Donati, C
    Douglas, JF
    Kob, W
    Plimpton, SJ
    Poole, PH
    Glotzer, SC
    [J]. PHYSICAL REVIEW LETTERS, 1998, 80 (11) : 2338 - 2341
  • [7] Supercooled liquids and glasses
    Ediger, MD
    Angell, CA
    Nagel, SR
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) : 13200 - 13212
  • [8] Relaxation in a glassy binary mixture: Comparison of the mode-coupling theory to a Brownian dynamics simulation
    Flenner, E
    Szamel, G
    [J]. PHYSICAL REVIEW E, 2005, 72 (03):
  • [9] Asymptotic laws for tagged-particle motion in glassy systems
    Fuchs, M
    Gotze, W
    Mayr, MR
    [J]. PHYSICAL REVIEW E, 1998, 58 (03): : 3384 - 3399
  • [10] Molecular dynamics simulation of the dynamics of supercooled silica
    Horbach, J
    Kob, W
    Binder, K
    [J]. PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1998, 77 (02): : 297 - 303