Determination of Lead with a Copper-Based Electrochemical Sensor

被引:131
作者
Kang, Wenjing [1 ]
Pei, Xing [1 ]
Rusinek, Cory A. [2 ]
Bange, Adam [4 ]
Haynes, Erin N. [3 ]
Heineman, William R. [2 ]
Papautsky, Ian [5 ]
机构
[1] Univ Cincinnati, Dept Elect Engn & Comp Syst, Cincinnati, OH 45221 USA
[2] Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA
[3] Univ Cincinnati, Dept Environm Hlth, Cincinnati, OH 45221 USA
[4] Xavier Univ, Dept Chem, Cincinnati, OH 45207 USA
[5] Univ Illinois, Dept Bioengn, Chicago, IL 60607 USA
基金
美国国家卫生研究院;
关键词
ANODIC-STRIPPING VOLTAMMETRY; ELEMENT ANALYSIS; TRACE-METALS; ELECTRODE; CADMIUM(II); CHILDREN; MERCURY; DEVICE;
D O I
10.1021/acs.analchem.6b03894
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This work dernonstrates'determination of lead (Pb) in surface water samples using a low-cost copper (Cu)-based electrochemical sensor. Heavy metals require careful monitoring due to their toxicity, yet current methods are too,complex or bulky for point-Of-care (POC) use. Electrochemistry offers a convenient.alternative for metal determination) but the traditional electrodes,, such as carbon or gold/platinum, are costly and difficult to tnidrofabricite. Our copper-based sensor features a low-cost electrode material-copper-that offers simple fabrication and competitive performance in electrochemical detection. For anodic stripping voltammetry (ASV) of Pb, our sensor shows 21 nM (4.4 ppb) limit of detection, resistance to interfering metals such as cadmium (Cd) and zinc (Zn), and stable response in. natural water samples with minimum sample pretreatment.. These results suggest this electrochemical sensor is suitable for environmental and potentially biological applications, where accurate and rapid, yet inexpensive, on-site monitoring is necessary.
引用
收藏
页码:3345 / 3352
页数:8
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