Luminescent ruthenium-polypyridine complexes & phosphorus ligands: anything but a simple story

被引：49

作者：

Dixon, Isabelle M. ^{[1
,2
]}

Lebon, Emilie ^{[1
,2
]}

Sutra, Pierre ^{[1
,2
]}

Igau, Alain ^{[1
,2
]}

机构：

[1] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France

[2] CNRS, LCC, F-31077 Toulouse, France

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 06期

关键词：

RU(II) BIPYRIDYL COMPLEXES; RIGID MOLECULAR RODS; RU-II; PHOTOPHYSICAL PROPERTIES; COORDINATION-COMPOUNDS; PHOTOSUBSTITUTION REACTIONS; SPECTROSCOPIC PROPERTIES; EXCITED-STATE; ELECTRONIC COMMUNICATION; PHOTOCHEMICAL REACTIVITY;

D O I：

10.1039/b804763b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This tutorial review presents an exhaustive picture of the luminescence studies that have been undertaken on ruthenium(II) complexes bearing polypyridine and phosphorus(III) ligands. The introduction of phosphorus to the Ru coordination sphere has multiple consequences on the nature and energy of the various excited states involved, but it does not necessarily rule out room temperature emission.

引用

页码：1621 / 1634

页数：14

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