Preparation and Photoluminescence Investigation of Organic-inorganic Hybrid Materials of Complex Ag2ClO5N5C28H22

被引：0
|
作者：
Gu Chang Sheng [1 ]
Hao Xiao Min [1 ]
Ji Li Li [2 ]
Li Yong [1 ]
Song Wen Dong [2 ]
机构：
[1] Guangdong Ocean Univ, Dept Appl Chem, Zhanjiang 524088, Peoples R China
[2] Zhejiang Ocean Univ, Innovat & Applicat Inst, Zhoushan 316022, Peoples R China
来源：
PROCEEDINGS OF THE 2015 INTERNATIONAL CONFERENCE ON ADVANCED ENGINEERING MATERIALS AND TECHNOLOGY | 2015年 / 38卷
关键词：
organic-inorganic hybrid materials; luminescent property; 2-Chlorobenzeneacetic acid; NITROGEN HETEROCYCLIC LIGANDS; CRYSTAL-STRUCTURES; COORDINATION POLYMER; H-2; ADSORPTION; ACID; FRAMEWORK; CD(II);
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
One new organic-inorganic hybrid materials of complex Ag2ClO5N5C28H22 (1) was synthesized by evaporation methods using 2-Chlorobenzeneacetic acid(2-CBAA), 4,4'-dipyridyl (4,4'-bipy), and AgNO3. And the complex was characterized by elemental analysis, FT-IR, thermogravimetrie analysis(TGA), XRD, X-ray single-crystal structure analysis and fluorescence properties have been studied. As a result, complex 1 are one-dimensional structure. Among others, Ag(I) ion is surrounded by two nitrogen atoms from two bipy ligands form an infinite chain, and adjacent Ag-bipy chains produce "rungs" of a ladder by silver ions contacts. Complex 1 emits the intensely luminescence with the fluorescence of 486 nm in a solid state at room temperature. CCDC: 1031206.
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页码：64 / 69
页数：6
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