Preparation and Photoluminescence Investigation of Organic-inorganic Hybrid Materials of Complex Ag2ClO5N5C28H22

One new organic-inorganic hybrid materials of complex Ag2ClO5N5C28H22 (1) was synthesized by evaporation methods using 2-Chlorobenzeneacetic acid(2-CBAA), 4,4'-dipyridyl (4,4'-bipy), and AgNO3. And the complex was characterized by elemental analysis, FT-IR, thermogravimetrie analysis(TGA), XRD, X-ray single-crystal structure analysis and fluorescence properties have been studied. As a result, complex 1 are one-dimensional structure. Among others, Ag(I) ion is surrounded by two nitrogen atoms from two bipy ligands form an infinite chain, and adjacent Ag-bipy chains produce "rungs" of a ladder by silver ions contacts. Complex 1 emits the intensely luminescence with the fluorescence of 486 nm in a solid state at room temperature. CCDC: 1031206.