Hydrogen bonding in ND3 probed by neutron diffraction to 24 GPa

被引：23

作者：

Ninet, S. ^{[1
]}

Datchi, F. ^{[1
]}

Klotz, S. ^{[1
]}

Hamel, G. ^{[1
]}

Loveday, J. S. ^{[2
,3
]}

Nelmes, R. J. ^{[2
,3
]}

机构：

[1] Univ Paris 06, CNRS, Inst Mineral & Phys Milieux Condenses, F-75015 Paris, France

[2] Univ Edinburgh, Ctr Sci Extreme Condit, Edinburgh EH9 3JZ, Midlothian, Scotland

[3] Univ Edinburgh, Sch Phys, SUPA, Edinburgh EH9 3JZ, Midlothian, Scotland

来源：

PHYSICAL REVIEW B | 2009年 / 79卷 / 10期

关键词：

ammonia; crystal structure; high-pressure solid-state phase transformations; hydrogen bonds; neutron diffraction; Raman spectra; HIGH-PRESSURE; ICE-VIII; SOLID AMMONIA; PHASE; SYMMETRIZATION; RAMAN; TRANSITION; IV;

D O I：

10.1103/PhysRevB.79.100101

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The structure of deuterated ammonia has been determined as a function of pressure up to 24 GPa using powder neutron-diffraction techniques. The presence of an isostructural transition at approximately 18 GPa is confirmed and ascribed to a slight displacement of one D atom. As a result, the H bond formed by this D atom changes angle and becomes nearly straight (178 degrees) at 24 GPa. A departure from the molecular C-3v symmetry is also detected which is further supported by the evolution of the Raman spectra.

引用

页数：4

共 50 条

[1] Neutron powder diffraction measurements on [Zn(ND3)(4)]I-2 at 1.5 K, 10 K, and 293 K: Hydrogen bonds and dynamic of ND3 molecules
Essmann, R
Fischer, P
Vogt, T
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (04): : 597 - 602
[2] Hydrogen bonding in ethanol - a high pressure neutron diffraction study
Bull, Craig L.
Barnett, Sarah A.
Allan, Dave R.
Marshall, William G.
HIGH PRESSURE RESEARCH, 2019, 39 (01) : 179 - 184
[3] A Neutron Diffraction and Quantum-Chemical Study of [Mn(ND3)6](N3)2
Ivlev, Sergei I.
Mueller, Thomas G.
Karttunen, Antti J.
Hoelzel, Markus
Kraus, Florian
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2018, 644 (21): : 1349 - 1353
[4] Observation of hydrogen bonding network in hydrogen sulfide hydrate using neutron diffraction
Hoshikawa, Akinori
Hachikubo, Akihiro
CHEMICAL PHYSICS LETTERS, 2023, 812
[5] The crystal structure of perdeuterated methanol monoammoniate (CD3OD•ND3) determined from neutron powder diffraction data at 4.2 and 180 K
Fortes, A. D.
Wood, I. G.
Knight, K. S.
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 : 1054 - 1061
[6] Uniaxial orientational order-disorder transitions in diammine magnesium halides, Mg(ND3)2Cl2 and Mg(ND3)2Br2, investigated by neutron diffraction
Leineweber, A
Jacobs, H
Fischer, P
Böttger, G
JOURNAL OF SOLID STATE CHEMISTRY, 2001, 156 (02) : 487 - 499
[7] Dispersion-Driven Hydrogen Bonding: Predicted Hydrogen Bond between Water and Platinum(II) Identified by Neutron Diffraction
Rizzato, Silvia
Berges, Jacqueline
Mason, Sax A.
Albinati, Alberto
Kozelka, Jiri
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (41) : 7440 - 7443
[8] Neutron diffraction study of hydrogen site occupancy in Fe0.95Si0.05 at 14.7 GPa and 800 K
Mori, Yuichiro
Kagi, Hiroyuki
Kakizawa, Sho
Komatsu, Kazuki
Shito, Chikara
Iizuka-Oku, Riko
Aoki, Katsutoshi
Hattori, Takanori
Sano-Furukawa, Asami
Funakoshi, Ken-ichi
Saitoh, Hirouyki
JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES, 2021, 116 (06) : 309 - 313
[9] Direct Determination of the Hydrogen Bonding Arrangement in Anhydrous β-Chitin by Neutron Fiber Diffraction
Sawada, Daisuke
Nishiyama, Yoshiharu
Langan, Paul
Forsyth, V. Trevor
Kimura, Satoshi
Wada, Masahisa
BIOMACROMOLECULES, 2012, 13 (01) : 288 - 291
[10] Deformability, inherent mechanical properties and chemical bonding of Al11 Nd3 in Al-Nd target material
Wang, Xue-Qian
Song, Run-Xin
Wang, Dong
Guan, Xu
Li, Shuan
Sun, Shuchen
Yang, Hongbo
Wang, Xiangjie
Wu, Daogao
Tu, Ganfeng
Li, Song
Yan, Hai-Le
Zuo, Liang
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2025, 214 : 278 - 291

← 1 2 3 4 5 →