Synthesis and Electrochemistry of Cadmium Complexes with OC(NH2)2, OS(CH3)2 and C6H5NE2 Ligands in Irreversible System

被引:0
作者
Haghighi, L. Zare [1 ]
Sadjadi, S. A. [1 ]
Milani, S. M. [1 ]
Tadjarodi, A. [1 ]
机构
[1] Iran Univ Sci & Technol, Coll Chem, Tehran, Iran
关键词
Cadmium complexes; Cyclic voltammetry; Irreversible behaviour; Au electrode; DIFFERENTIAL-PULSE POLAROGRAPHY; CYCLIC VOLTAMMETRY; BEHAVIOR; LEAD(II); NADH;
D O I
暂无
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Cd[OC(NH2)(2)](4)(NO3)(2), Cd(C6H5NH2)(2)(NO3)(2) and Cd[OS(CH3)(2)](2)(NO3)(2) are synthesized and identified by spectroscopic methods. The electrochemical behaviour of complexes is studied by cyclic voltammetry on Au electrode. The complexes exhibit irreversible behavior in presence of KNO3 0.05moll(-1) as a supporting electrolyte. Consequently the parameters of apparent transfer, diffusion coefficient, the standard Gibbs energiy of activation and the standard electron transfer constant are calculated.
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页码:223 / 231
页数:9
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