The first example of the ortho-directing effect of the weakly coordinating substituent [-BF3]- in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion

被引：15

作者：

Adonin, Nicolay Yu. ^{[1
]}

Prikhod'ko, Sergey A. ^{[1
]}

Bardin, Vadim V. ^{[2
]}

Parmon, Valentin N. ^{[1
]}

机构：

[1] Russian Acad Sci, GK Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

[2] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2009年 / 19卷 / 05期

关键词：

C-F BOND; CARBON FLUORINE BONDS; CRYSTAL-STRUCTURE; CYCLOMETALLATION REACTIONS; INTRAMOLECULAR ACTIVATION; PHOSPHINE COMPLEXES; NICKEL-COMPLEXES; METAL-COMPLEXES; LEWIS-ACIDS; H BONDS;

D O I：

10.1016/j.mencom.2009.09.009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pentafluorophenyltrifluoroborate anion undergoes hydrodefluorination under the action of zinc in the presence of nickel complexes turning into the 2,3,4,5-tetrafluoroborate anion.

引用

页码：260 / 262

页数：3

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