Magnetic kaolinite immobilized chitosan beads for the removal of Pb(II) and Cd(II) ions from an aqueous environment

被引:82
作者
Elanchezhiyan, S. Sd [1 ]
Karthikeyan, Perumal [2 ]
Rathinam, Karthik [3 ]
Farzana, M. Hasmath [4 ]
Park, Chang Min [1 ]
机构
[1] Kyungpook Natl Univ, Dept Environm Engn, 80 Daehak Ro, Daegu 41566, South Korea
[2] Gandhigram Rural Inst Deemed Univ, Dept Chem, Dindigul 624302, Tamil Nadu, India
[3] Univ Duisburg Essen, Chair Mech Proc Engn & Water Technol, Lotharstr 1, D-47057 Duisburg, Germany
[4] Madura Coll Autonomous, Dept Chem, Madurai 625011, Tamil Nadu, India
基金
新加坡国家研究基金会;
关键词
Chitosan; Kaolinite; Magnetic beads; Lead; Cadmium; HEAVY-METAL IONS; WASTE-WATER; ADSORPTION BEHAVIOR; EFFICIENT REMOVAL; LEAD REMOVAL; CADMIUM; NANOPARTICLES; EXCHANGE; EQUILIBRIUM; PERFORMANCE;
D O I
10.1016/j.carbpol.2021.117892
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In recent decades, magnetic bead material has attracted considerable attention in water and wastewater purification. In this study, the potential of magnetic kaolinite immobilized in chitosan beads (MKa@CB) to remove Pb(II) and Cd(II) ions from an aqueous environment has been successfully investigated. The addition of magnetic kaolinite generates more active sites, whereas that of chitosan enhances the stability of synthesized bead materials, which enable them to effectively interact with the targeted contaminants. Various factors including agitation time, solution pH, and competitive ions were examined to optimize the removal efficiency of the MKa@CB. The adsorption kinetics and isotherm studies indicated that the adsorption fitted well to the pseudosecond-order kinetic model as well as to the Langmuir isotherm. The prepared adsorbent could be reused up to four cycles without any significant adsorption capacity loss. Thus, the synthesized MKa@4%CB can be a promising adsorbent in effectively removing Pb(II) and Cd(II) from water.
引用
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页数:11
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