Use of 4-piperidones in one-pot syntheses of novel, high-molecular-weight linear and virtually 100%-hyperbranched polymers

被引：35

作者：

Cruz, Alfredo R. ^{[1
]}

Zolotukhin, Mikhail G. ^{[1
]}

Morales, Salvador L. ^{[1
]}

Cardenas, Jorge ^{[3
]}

Cedillo, Gerardo ^{[1
]}

Fomine, Serguei ^{[1
]}

Salmon, Manuel ^{[3
]}

Carreon-Castro, Maria P. ^{[2
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Invest Mat, Mexico City 04510, DF, Mexico

[2] Univ Nacl Autonoma Mexico, Inst Ciencias Nucl, Mexico City 04510, DF, Mexico

[3] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 29期

关键词：

HYPERBRANCHED POLYMERS; 100-PERCENT; ACTIVATION;

D O I：

10.1039/b907042g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

4-Piperidone and 4-alkyl piperidones react selectively with aromatic hydrocarbons in a mixture of trifluoromethanesulfonic acid (TFSA) and CH2Cl2 to give linear polymers, while N-(2-phenethyl)-piperidone undergoes self-polymerization to yield virtually 100%-hyperbranched polymer.

引用

页码：4408 / 4410

页数：3

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