Investigation of phases in the carbon films deposited by electrolysis of ethanol liquid phase using Raman scattering

被引:28
作者
Sun, Z [1 ]
Sun, Y
Wang, X
机构
[1] Nanyang Technol Univ, Sch Elect & Elect Engn, Singapore 639798, Singapore
[2] NYU, Dept Chem, New York, NY 10003 USA
[3] Texas Tech Univ, Dept Phys, Lubbock, TX 79409 USA
关键词
D O I
10.1016/S0009-2614(00)00041-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A carbon film was deposited on Si substrate from an ethanol liquid phase by electrolysis at low temperature (60 degrees C) in ambient atmosphere, and various carbon phases in the film were investigated by micro-Raman spectroscopy. Raman spectroscopy analysis confirmed the crystalline diamond structure by the presence of a sharp peak at 1331 cm(-1). Meanwhile, short-chain polyethylene, hydrogenated amorphous diamond-like and glassy carbon phases were found in the films. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:471 / 475
页数:5
相关论文
共 15 条
[1]  
BRANDRUP J, 1989, POLYM HDB
[2]   MAN-MADE DIAMONDS [J].
BUNDY, FP ;
HALL, HT ;
STRONG, HM ;
WENTORF, RH .
NATURE, 1955, 176 (4471) :51-55
[3]   CHARACTERIZATION OF DIAMOND FILMS BY RAMAN-SPECTROSCOPY [J].
KNIGHT, DS ;
WHITE, WB .
JOURNAL OF MATERIALS RESEARCH, 1989, 4 (02) :385-393
[4]   Chemical vapor deposition of diamond growth using a chemical precursor [J].
Leroy, E ;
Kuttel, OM ;
Schlapbach, L ;
Giraud, L ;
Jenny, T .
APPLIED PHYSICS LETTERS, 1998, 73 (08) :1050-1052
[5]  
Lin-Vien D., 1991, The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules
[6]   ALKYL MONOLAYERS ON SILICON PREPARED FROM 1-ALKENES AND HYDROGEN-TERMINATED SILICON [J].
LINFORD, MR ;
FENTER, P ;
EISENBERGER, PM ;
CHIDSEY, CED .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (11) :3145-3155
[7]   ALKYL MONOLAYERS COVALENTLY BONDED TO SILICON SURFACES [J].
LINFORD, MR ;
CHIDSEY, CED .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (26) :12631-12632
[8]   ATTEMPT TO GROW DIAMOND PHASE CARBON-FILMS FROM AN ORGANIC SOLUTION [J].
NAMBA, Y .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1992, 10 (05) :3368-3370
[9]   RAMAN-SCATTERING CHARACTERIZATION OF CARBON BONDING IN DIAMOND AND DIAMONDLIKE THIN-FILMS [J].
NEMANICH, RJ ;
GLASS, JT ;
LUCOVSKY, G ;
SHRODER, RE .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 1988, 6 (03) :1783-1787
[10]   Synthesis of diamondlike films by an electrochemical method at atmospheric pressure and low temperature [J].
Novikov, VP ;
Dymont, VP .
APPLIED PHYSICS LETTERS, 1997, 70 (02) :200-202