Magnetocaloric effect in bulk and nanostructured Gd3Fe5O12 materials

被引:75
作者
Phan, M. H. [1 ]
Morales, M. B. [1 ]
Chinnasamy, C. N. [2 ,3 ]
Latha, B. [2 ,3 ]
Harris, V. G. [2 ,3 ]
Srikanth, H. [1 ]
机构
[1] Univ S Florida, Dept Phys, Tampa, FL 33620 USA
[2] Northeastern Univ, CM3IC, Boston, MA 02115 USA
[3] Northeastern Univ, Dept Elect & Comp Engn, Boston, MA 02115 USA
基金
美国国家科学基金会;
关键词
MAGNETIC-PROPERTIES;
D O I
10.1088/0022-3727/42/11/115007
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report here the magnetocaloric effect (MCE) in bulk and nanostructured gadolinium iron garnets (Gd3Fe5O12). When compared with the bulk counterpart, the magnitude of the MCE is smaller for nanostructured samples with an average grain size of 50 nm, but increases when the grain size decreases to 35 nm. For the bulk sample, the MCE curves show a broad peak at 35 K; this peak is found to shift to lower temperatures for the nanostructured samples. The origin of the MCE peak for the bulk sample is associated with the intrinsic magnetic frustration and the ferromagnetic ordering of the Gd sublattice below 90K, while for nanostructured garnets it is additionally ascribed to the surface spin disorder and particle blocking effects. While blocking is detrimental to achieving large MCE, surface spin disorder is found to enhance it under high applied fields.
引用
收藏
页数:7
相关论文
共 33 条
[1]   Magnetocaloric effects in magnetic nanoparticle systems:: A Monte Carlo study [J].
Baldomir, D. ;
Rivas, J. ;
Serantes, D. ;
Pereiro, M. ;
Arias, J. E. ;
Bujan-Nunez, M. C. ;
Vasquez-Vazquez, C. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (8-10) :790-792
[2]  
BELOV KN, 1969, JETP LETT-USSR, V9, P416
[3]   Magnetocaloric effect in random magnetic anisotropy materials [J].
Bohigas, X ;
Tejada, J ;
Torres, F ;
Arnaudas, JI ;
Joven, E ;
del Moral, A .
APPLIED PHYSICS LETTERS, 2002, 81 (13) :2427-2429
[4]   Developments in magnetocaloric refrigeration [J].
Brück, E .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2005, 38 (23) :R381-R391
[5]   The magnetocaloric effect in high-spin paramagnetic rare-earth fluorites [J].
Fernandez, Antonio ;
Bohigas, Xavier ;
Tejada, Javier ;
Sulyanova, Elena A. ;
Buchinskaya, Irina I. ;
Sobolev, Boris P. .
MATERIALS CHEMISTRY AND PHYSICS, 2007, 105 (01) :62-66
[6]   Tailoring of magnetocaloric response in nanostructured materials: Role of anisotropy [J].
Franco, Victorino ;
Pirota, Kleber R. ;
Prida, Victor M. ;
Neto, Antonio Maia J. C. ;
Conde, Alejandro ;
Knobel, Marcelo ;
Hernando, Blanca ;
Vazquez, Manuel .
PHYSICAL REVIEW B, 2008, 77 (10)
[7]   Large magnetocaloric effect in La(FexSi1-x)13 itinerant-electron metamagnetic compounds [J].
Fujieda, S ;
Fujita, A ;
Fukamichi, K .
APPLIED PHYSICS LETTERS, 2002, 81 (07) :1276-1278
[8]   Magnetization and magnetocaloric effect in ball-milled zinc ferrite powder [J].
Gass, J. ;
Srikanth, H. ;
Kislov, N. ;
Srinivasan, S. S. ;
Emirov, Y. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (07)
[9]   Static and dynamic magnetic properties of spherical magnetite nanoparticles [J].
Goya, GF ;
Berquó, TS ;
Fonseca, FC ;
Morales, MP .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (05) :3520-3528
[10]   Effects of ball milling on the grain morphology and the magnetic properties of Gd3Fe3Al2O12 garnet compound [J].
Grasset, F ;
Mornet, S ;
Etourneau, J ;
Haneda, H ;
Bobet, JL .
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 359 :330-337