Synthesis and Characterization of Cu-Doped Zirconium Titanate as A Potential Visible-Light Responsive Photocatalyst

被引:6
作者
Andita, Katarina Rachma [1 ]
Kurniawan, Rian [1 ]
Syoufian, Akhmad [1 ]
机构
[1] Univ Gadjah Mada, Fac Math & Nat Sci, Dept Chem, Sekip Utara 55281, Yogyakarta, Indonesia
关键词
copper; dopant; Cu-doped ZrTiO4; photocatalyst; sol-gel; TIO2; ZRO2; DEGRADATION; FILMS;
D O I
10.22146/ijc.39778
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis and characterization of Cu-doped zirconium titanate as a potential visible-light responsive photocatalyst had been conducted. Titanium tetraisopropoxide (TTIP) was used as a precursor of Ti source, reacted to ZrO2 powder and CuSO4 center dot 5H(2)O with various Cu concentrations of 0, 1, 3, 5, 7 and 9% (w/w) by sol-gel method. Zirconium titanate with Cu concentration of 5% was calcined at various temperatures of 500, 700 and 900 degrees C. All materials were characterized by using XRD, FTIR, SRUV, and SEM-EDX. The characterization proved that the materials were potential as a model of visible-light responsive photocatalyst. Composite with optimum bandgap energy (E-g) was obtained at 5% Cu content after 500 degrees C with an absorption edge wavelength of 431.93 nm and the bandgap of 2.87 eV.
引用
收藏
页码:761 / 766
页数:6
相关论文
共 18 条
  • [1] Enhanced visible-light photocatalytic activity of multi-elements-doped ZrO2 for degradation of indigo carmine
    Agorku, E. S.
    Kuvarega, A. T.
    Mamba, B. B.
    Pandey, A. C.
    Mishra, A. K.
    [J]. JOURNAL OF RARE EARTHS, 2015, 33 (05) : 498 - 506
  • [2] Andita K. R., 2018, THESIS
  • [3] Photocatalytic properties of ZrO2 and Fe/ZrO2 semiconductors prepared by a sol-gel technique
    Botta, SG
    Navío, JA
    Hidalgo, MC
    Restrepo, GM
    Litter, MI
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1999, 129 (1-2) : 89 - 99
  • [4] The effect of chemical states of dopants on the microstructures and band gaps of metal-doped ZrO2 thin films at different temperatures
    Chang, SM
    Doong, RA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (46) : 18098 - 18103
  • [5] Effect of Grain Size on Phase Transformation and Photoluminescence Property of the Nanocrystalline ZrO2 Powders Prepared by Sol-Gel Method
    Chen, Qiong
    Chang, Yongqin
    Shao, Changjing
    Zhang, Jing
    Chen, Jun
    Wang, Mingwen
    Long, Yi
    [J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2014, 30 (11) : 1103 - 1107
  • [6] Effects of Single Metal-Ion Doping on the Visible-Light Photoreactivity of TiO2
    Choi, Jina
    Park, Hyunwoong
    Hoffmann, Michael R.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (02) : 783 - 792
  • [7] The photocatalytic removal of bacterial pollutants from drinking water
    Dunlop, PSM
    Byrne, JA
    Manga, N
    Eggins, BR
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) : 355 - 363
  • [8] Highly dispersed sol-gel synthesized Cu-ZrO2 materials as catalysts for oxidative steam reforming of methanol
    Esposito, Serena
    Turco, Maria
    Bagnasco, Giovanni
    Cammarano, Claudia
    Pernice, Pasquale
    Aronne, Antonio
    [J]. APPLIED CATALYSIS A-GENERAL, 2010, 372 (01) : 48 - 57
  • [9] Synthesis and characterization of Cu-ZrO2 nanocomposite produced by thermochemical process
    Fathy, Adel
    Elkady, Omayma
    Abu-Oqail, Ahmed
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 719 : 411 - 419
  • [10] Exploring potential Environmental applications of TiO2 Nanoparticles
    Haider, Adawiya J.
    Al-Anbari, Riyad Hassan
    Kadhim, Ghadah Rasim
    Salame, Chafic Touma
    [J]. INTERNATIONAL CONFERENCE ON TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY, TMREES17, 2017, 119 : 332 - 345