A new rhodium complex with a nitrogen-containing bis (phosphine oxide) ligand as an efficient catalyst for the hydroformylation of styrene

被引：16

作者：

Tolis, Evangelos I. ^{[1
]}

Vallianatou, Kalliopi A. ^{[1
]}

Andreadaki, Fotini J. ^{[1
]}

Kostas, Ioannis D. ^{[1
]}

机构：

[1] Natl Hellen Res Fdn, Inst Organ & Pharmaceut Chem, Athens 11635, Greece

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2006年 / 20卷 / 05期

关键词：

amino phosphine oxide; bis(phosphine oxide); hemilabile ligand; rhodium complex; hydroformylation; homogeneous catalysis;

D O I：

10.1002/aoc.1057

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new rhodium complex with a nitrogen-containing bis(phosphine oxide) ligand has been synthesized. The complex was applied to hydroformylation of styrene and displayed high activity and regioselectivity towards the branched aldehyde, which was found to be higher than those of the tertiary bis(phosphine) analogue. Copyright (c) 2006 John Wiley & Sons, Ltd.

引用

页码：335 / 337

页数：3

共 20 条

[1] PHOSPHINE VS PHOSPHINE OXIDE LIGANDS IN HYDROFORMYLATION REACTIONS [J].

ABUGNIM, C ;

AMER, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) :115-117

[2] Phosphine oxides as ligands in the hydroformylation reaction [J].

AbuGnim, C ;

Amer, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 516 (1-2) :235-243

[3] HYDROFORMYLATION OF SOME FUNCTIONALIZED OLEFINS CATALYZED BY RHODIUM(I) COMPLEXES WITH PYDIPHOS AND ITS P-OXIDE [J].

BASOLI, C ;

BOTTEGHI, C ;

CABRAS, MA ;

CHELUCCI, G ;

MARCHETTI, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 488 (1-2) :C20-C22

[4] CYCLOOCTATETRAENE-RHODIUM(I) COMPLEXES [J].

BENNETT, MA ;

SAXBY, JD .

INORGANIC CHEMISTRY, 1968, 7 (02) :321-&

[5]

Börner A, 2001, EUR J INORG CHEM, P327

[6]

Braunstein P, 2001, ANGEW CHEM INT EDIT, V40, P680, DOI 10.1002/1521-3773(20010216)40:4<680::AID-ANIE6800>3.0.CO

[7]

2-0

[8]

Frohning C.D., 1996, Applied Homogeneous Catalysis with Organometallic Compounds, V1, P29

[9] DI-MU-CHLORO-BIS(ETA-4-1,5-CYCLOOCTADIENE)DIRHODIUM(I) [J].

GIORDANO, G ;

CRABTREE, RH .

INORGANIC SYNTHESES, 1990, 28 :88-90

[10] CATIONIC TRANSITION-METAL COMPLEXES .1. SYNTHESIS AND REACTIONS OF BIS(DIENE)-RHODIUM AND BIS(DIENE)-IRIDIUM TETRAFLUOROBORATES [J].

GREEN, M ;

KUC, TA ;

TAYLOR, SH .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (14) :2334-&

← 1 2 →