Seed-Induced Crystallization of Nanosized Na-ZSM-5 Crystals

被引：238

作者：

Majano, Gerardo ^{[1
]}

Darwiche, Ali ^{[2
]}

Mintova, Svetlana ^{[1
]}

Valtchev, Valentin ^{[1
]}

机构：

[1] Univ Caen, ENSICAEN, Catalyse & Spectrochim Lab, CNRS, F-14050 Caen, France

[2] CEA Saclay, DEN, DANS, DPC,SCP,LRSI, F-91191 Gif Sur Yvette, France

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2009年 / 48卷 / 15期

关键词：

ZEOLITE NANOCRYSTALS; ROOM-TEMPERATURE; COLLOIDAL SUSPENSIONS; MECHANISM; NUCLEATION; ZSM-5; TEMPLATE; TPA-SILICALITE-1; SCATTERING; GROWTH;

D O I：

10.1021/ie8017252

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

ZSM-5 nanocrystals were synthesized from organic-template free gel systems containing 0.1, 1.0,and 3.0 wt% of 80 nm silicalite-1 seeds. The syntheses were performed at 100, 120, 150, and 170 degrees C for periods of time ranging between 3 and 190 h. Physicochemical characteristics derived from XRD, NMR, TG/DTA, SEM/TEM, DLS, N-2, adsorption and chemical analyses of Na-ZSM-5 nanocrystals were compared with those of the nanosized tetrapropylammonium (TPA)-promoted counterpart. Crystalline yield and colloidal stability of ZSM-5 nanosized materials obtained under different conditions (seed content, crystallization temperature, and time) were also studied. Another issue: of interest in the framework of this study was the effect of seed pretreatment (drying, calcination) on the characteristics of crystalline product. Thus, factors controlling seeded growth of nanosized zeolite particles were established and the mechanism of formation, including parameters governing the formation of single or aggregated crystals, revealed.

引用

页码：7084 / 7091

页数：8

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