Thermal stability of polymer derived SiBNC ceramics

被引：44
作者：
Tang, Yun [1 ]
Wang, Jun [1 ]
Li, Xiaodong [1 ]
Li, Wenhua [1 ]
Wang, Hao [1 ]
Wang, Xiaozhou [1 ]
机构：
[1] Natl Univ Def Technol, State Key Lab Adv Ceram Fibers & Composite, Changsha 410073, Hunan, Peoples R China
来源：
CERAMICS INTERNATIONAL | 2009年 / 35卷 / 07期
基金：
国家高技术研究发展计划(863计划);
关键词：
Calcination; X-ray methods; Thermal properties; Si-B-N-C ceramics; HIGH-TEMPERATURE STABILITY; SINGLE-SOURCE PRECURSOR; BORON CONTENT; BEHAVIOR; CARBON; POLYSILAZANE; FIBERS;
D O I：
10.1016/j.ceramint.2009.03.043
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
To study the thermal stability of polymer derived SiBNC ceramics, a polyborosilazane was pyrolyzed in N-2 and NH3/N-2 atmosphere, respectively. The as-pyrolyzed products were annealed in N-2 atmosphere at 1200-1850 degrees C for 2 h. The chemical composition and phase structure of the as-pyrolyzed and annealed ceramics were investigated by element analysis, XRD and FT-IR. The results show that all the ceramics exhibit excellent high temperature stability. They are fully amorphous to 1700 degrees C, and only partial crystallization, giving a mixture Of Si3N4, BN and SiC phases, is observed upon heating at 1850 degrees C. The N-2 pyrolyzed products show better stability than the NH3/N-2 pyrolyzed products and have less tendency to crystalline at higher temperatures. Better retention of nitrogen at high temperatures is also observed for the N-2 pyrolyzed products. (C) 2009 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码：2871 / 2876
页数：6
相关论文
共 30 条
  • [1] Ceramic fibers for matrix composites in high-temperature engine applications
    Baldus, P
    Jansen, M
    Sporn, D
    [J]. SCIENCE, 1999, 285 (5428) : 699 - 703
  • [2] Boron-modified polysilazane as a novel single-source precursor for SiBCN ceramic fibers: synthesis melt-sinning, curing and ceramic conversion
    Bernard, S
    Weinmann, M
    Gerstel, P
    Miele, P
    Aldinger, F
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (02) : 289 - 299
  • [3] PYROLYSIS OF PRECERAMIC POLYMERS IN AMMONIA - PREPARATION OF SILICON-NITRIDE POWDERS
    BURNS, GT
    CHANDRA, G
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (02) : 333 - 337
  • [4] High-temperature mechanical properties of Si-B-C-N-precursor-derived amorphous ceramics and the applicability of deformation models developed for metallic glasses
    Christ, M
    Thurn, G
    Weinmann, M
    Bill, J
    Aldinger, F
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2000, 83 (12) : 3025 - 3032
  • [5] In-situ carbon content adjustment in polysilazane derived amorphous SiCN bulk ceramics
    Galusek, D
    Reschke, S
    Riedel, R
    Dressler, W
    Sajgalík, P
    Lenceés, Z
    Majling, J
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (10) : 1911 - 1921
  • [6] Synthesis and high-temperature behavior of Si/B/C/N precursor-derived ceramics without "free carbon"
    Gerstel, P
    Müller, A
    Bill, J
    Aldinger, F
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (26) : 4980 - 4986
  • [7] A construction kit for Si-B-C-N ceramic materials based on borazine precursors
    Haberecht, J
    Nesper, R
    Grützmacher, H
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (09) : 2340 - 2347
  • [8] High-yield molecular borazine precursors for Si-B-N-C ceramics
    Haberecht, J
    Krumeich, F
    Grützmacher, H
    Nesper, R
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (03) : 418 - 423
  • [9] Silicon carbonitride ceramics derived from polysilazanes Part II. Investigation of electrical properties
    Haluschka, C
    Engel, C
    Riedel, R
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2000, 20 (09) : 1365 - 1374
  • [10] Structure and electronic transport properties of Si-(B)-C-N ceramics
    Hermann, AM
    Wang, YT
    Ramakrishnan, PA
    Balzar, D
    An, LN
    Haluschka, C
    Riedel, R
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2001, 84 (10) : 2260 - 2264
123