Preparation and infrared spectroscopic examination of Hofmann-type di- and triethanolamine complexes

被引：14

作者：

Karadag, A ^{[1
]}

Yilmaz, VT ^{[1
]}

机构：

[1] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Samsun, Turkey

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2000年 / 30卷 / 02期

关键词：

D O I：

10.1080/00945710009351768

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel di- and triethanolamine metal complexes with tetracyanonickelate(II) have been prepared and characterized by elemental analyses, magnetic moment and IR spectroscopy. The experimental data indicate that the structures of the complexes are analogous to those of Hofmann-type hosts, and consist of infinite polymeric layers of [M(L)Ni(CN)(4)] (where M = Co, Ni, Cu, Zn, Cd, and L = di- or triethanolamine). The ethanolamines behave as N- and O-donor bidentate ligands. The IR spectra show all principal features for DEAH(2) and TEAH(3)-metal complexes. The copper complexes have infrared spectra different from the other complexes due to the Jahn-Teller effect.

引用

页码：359 / 368

页数：10

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