Near infrared absorptions of CH4/He plasma:: the Phillips band system of C2

被引:18
作者
Chan, MC [1 ]
Yeung, SH [1 ]
Wong, YY [1 ]
Li, YF [1 ]
Chan, WM [1 ]
Yim, KH [1 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
关键词
D O I
10.1016/j.cplett.2004.03.139
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Zero-background laser absorption spectroscopy using concentration modulation has been applied to study the near infrared absorption spectrum of the discharge of CH4 and He at a ratio of about 1:170. In the 10300-14250 cm(-1) region, a total of 13 vibronic bands have been observed with 11 of them assigned to the very weak Phillips band system of C-2. Combining these transitions with those observed in emission by Douay et al. [J. Mol. Spectrosc. 131 (1988) 250], a set of spectroscopic constants with high accuracy have been obtained. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:340 / 346
页数:7
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