Phosphorus-, sulfur-, and nitrogen-containing ligands in complexes with copper(I) halides

被引：0

作者：

Kursheva, LI ^{[1
]}

Il'in, AM ^{[1
]}

Dzhidzalova, YG ^{[1
]}

Batyeva, ES ^{[1
]}

机构：

[1] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, Kazan Sci Ctr, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 1999年 / 69卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions between mixed phosphorous acid esters containing P-N, P-S and P-N, P-O bonds with Cu(I) halides yield a series of new P,S,N,O-containing metal complexes. Phosphoroamidothioite complexes are unstable and easily disproportionate in the metal coordination sphere to give stable compounds containing symmetrical phosphorotrithioite and phosphorous triamide ligands. The structure of the compound (EtS)(2)PNE2 . CuBr was studied by X-ray diffraction. In this complex monodentate coordination via phosphorus and bidentate coordination via phosphorus and sulfur are observed simultaneously.

引用

页码：880 / 882

页数：3