Tuning of nonlinear optical and ferroelectric properties via the cationic composition of Ca9.5-1.5xBixCd(VO4)7 solid solutions

被引：22
作者：
Dorbakov, N. G. [1 ]
Baryshnikova, O. V. [1 ]
Morozov, V. A. [1 ]
Belik, A. A. [2 ]
Katsuya, Y. [3 ]
Tanaka, M. [3 ]
Stefanovich, S. Yu. [1 ]
Lazoryak, B. I. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[2] Natl Inst Mat Sci, Funct Mat Res Ctr, Namiki 1-1, Tsukuba, Ibaraki 3050044, Japan
[3] Natl Inst Mat Sci, Synchrotron Xray Stn, SPring 8, Kouto 1-1-1, Sayo, Hyogo 6795148, Japan
来源：
MATERIALS & DESIGN | 2017年 / 116卷
基金：
俄罗斯科学基金会;
关键词：
Vanadates; Ferroelectric properties; Nonlinear optical properties; Crystal structure; CRYSTAL-STRUCTURE; PHASE-TRANSITION; METAL IODATES; WHITLOCKITE; SYSTEM; GROWTH; PHOTOLUMINESCENCE; PHOSPHORS; CALCIUM; MG;
D O I：
10.1016/j.matdes.2016.11.107
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Ca9.5-1.5xBixCd(VO4)(7) (0 <= x 1) solid solutions with the whitlockite-type structure (SG R3c) were synthesized by a standard solid-state method in air. Structures of Ca9.5-1.5xBixCd(VO4)(7) (x = 0.167, 0.5, 0.833) were refined by the Rietveld method from synchrotron powder X-ray diffraction data. Nonlinear optical properties of the whitlockite-type compounds can be designed and increased by an order of magnitude through appropriate isovalent and aliovalent substitutions for Ca2+ cations. Dielectric and temperature second harmonic generation investigations revealed the presence of a reversible ferroelectric phase transition in the range from 1331 K to 1055 K. The phase transition temperature monotonically decreases while nonlinear optical activity of Ca9.5-1.5xBixCd(VO4)(7) strongly increases with increasing Bi3+ content. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：515 / 523
页数：9
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