Determination of inorganic and organic tin in water samples by graphite furnace atomic absorption spectrometry

被引:0
作者
He, B [1 ]
Wu, D [1 ]
Jiang, GB [1 ]
机构
[1] Acad Sinica, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China
关键词
solvent extraction; hydride generation; graphite furnace atomic absorption spectrometry; organotin; inorganic tin;
D O I
暂无
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
This paper proposed a method for the determination of inorganic tin and organotin species. Total tin contents can be directly detected by zirconium-coated graphite furnace atomic absorption spectrometry, while the organotin was detected by hydride generation combined with solvent extraction and the difference between the total tin and organotin was inorganic tin. The detection limits were 58 pg and 27 pg for organotin and inorganic tin, respectively. The relative standard deviations of this procedure,were 2.13% and 2.04% , respectively. Several water samples were analyzed by this method. The recoveries ranging from 90.5% and 98.5% were obtained.
引用
收藏
页码:718 / 720
页数:3
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