Nanoscale spherical architectures fabricated by metal coordination of multiple dipyrrin moieties

被引：159

作者：

Maeda, Hiromitsu ^{[1
]}

Hasegawa, Masahiro

Hashimoto, Takashi

Kakimoto, Takuya

Nishio, Satoru

Nakanishi, Takashi

机构：

[1] Ritsumeikan Univ, Dept Biosci & Biotechnol, Kusatsu 5258577, Japan

[2] Ritsumeikan Univ, Dept Appl Chem, Fac Sci & Engn, Kusatsu 5258577, Japan

[3] Inst Mol Sci, Dept Appl Mol Sci, Okazaki, Aichi 4448787, Japan

[4] Natl Inst Mat Sci, Supermol Grp, Organ Nanomat Ctr, Tsukuba, Ibaraki 3050044, Japan

[5] Natl Inst Mat Sci, ICYS, Tsukuba, Ibaraki 3050044, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 31期

关键词：

D O I：

10.1021/ja0637301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phenylethynyl-bridged dipyrrin "dimers" have performed ZnII complexation to give coordination polymers, which provided the fluorescent colloidal spherical objects in solution as well as on the substrate according to the spacer units. Using a mixture of THF and water, unique morphologies, such as bell-shaped and "golf ball"-like architectures, were observed. Copyright © 2006 American Chemical Society.

引用

页码：10024 / 10025

页数：2

共 28 条

[1] Synthesis, derivatization and structural characterization of octahedral tris(5-phenyl-4,6-dipyrrinato) complexes of cobalt(III) and iron(III) [J].

Bruckner, C ;

Zhang, YJ ;

Rettig, SJ ;

Dolphin, D .

INORGANICA CHIMICA ACTA, 1997, 263 (1-2) :279-286

[2] Synthesis and self-assembly of novel tetra- and hexapyrroles containing dipyrrins linked by a sulfur bridge at the β-position [J].

Chen, QQ ;

Zhang, YJ ;

Dolphin, D .

TETRAHEDRON LETTERS, 2002, 43 (46) :8413-8416

[3]

Ciferri A, 2000, SUPRAMOLECULAR POLYMERS, P1

[4] Metallosupramolecular approach toward functional coordination polymers [J].

Dobrawa, R ;

Würthner, F .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (21) :4981-4995

[5]

Falk H., 1989, The Chemistry of Linear Oligopyrroles and Bile Pigments

[6] Molecular paneling via coordination [J].

Fujita, M ;

Umemoto, K ;

Yoshizawa, M ;

Fujita, N ;

Kusukawa, T ;

Biradha, K .

CHEMICAL COMMUNICATIONS, 2001, (06) :509-518

[7] Synthesis, structure, and spectroscopy of phenylacetylenylene rods incorporating meso-substituted dipyrrin ligands [J].

Halper, SR ;

Cohen, SM .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (19) :4661-4669

[8]

HAPLER SR, 2005, INORG CHEM, V44, P486

[9] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[10] Dipyrrin-porphyrin hybrids:: Potential π-conjugated platform to fabricate coordination oligomers [J].

Maeda, H ;

Ito, M .

CHEMISTRY LETTERS, 2005, 34 (08) :1150-1151

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