Improved synthesis of 1,4-phenanthrenequinones from Diels-Alder cycloadditions of 2-(p-tolylsulfinyl)-1,4-benzoquinone

被引：25

作者：

Carreno, MC

Mahugo, J

Urbano, A

机构：

[1] Depto. de Quim. Organ. (C-I), Universidad Autónoma, Cantoblanco

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(97)00505-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A wide range of substituted 1,4-phenanthrenequinones 5a-g and benz[c]- and benz[a]-1,4-phenanthrenequinones (5h) and (5i) were synthezised in one step through Diels-Alder cycloadditions of 2-(p-tolylsulfinyl)-1,4-benzoquinone 2 and vinylaromatic derivatives 1a-i under thermal and high pressure conditions in moderate to good yields (33-80%). (C) 1997 Elsevier Science Ltd.

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页码：3047 / 3050

页数：4

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