ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
|
2002年
/
57卷
/
07期
关键词:
D O I:
10.1515/znb-2002-0702
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Syntheses of the homoleptic trimethylsilanolato complexes V(OSiMe3)(3) and V(OSiMe3)(4) are described. The thiovanadium(V)compound VS(OSiPh3)(3) (11) is formed from [V(OSiPh3)(3)-(THF)(2)] upon oxidation with elemental sulfur; 11 has been characterized by V-51 NMR spectroscopy.