Silanolato complexes of vanadium (III, IV)

被引：1

作者：

Preuss, F ^{[1
]}

Werle, P ^{[1
]}

机构：

[1] Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2002年 / 57卷 / 07期

关键词：

D O I：

10.1515/znb-2002-0702

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Syntheses of the homoleptic trimethylsilanolato complexes V(OSiMe3)(3) and V(OSiMe3)(4) are described. The thiovanadium(V)compound VS(OSiPh3)(3) (11) is formed from [V(OSiPh3)(3)-(THF)(2)] upon oxidation with elemental sulfur; 11 has been characterized by V-51 NMR spectroscopy.

引用

页码：726 / 730

页数：5

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