Synthesis of Volatile Copper(II) β-Diketonates, β-Ketiminates, and β-Diiminates. The Problem of Synthesis of Copper(II) Bis(2,2,6,6-tetramethyl-3-methylaminoheptane-5-onate)

被引：6

作者：

Stabnikov, P. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2013年 / 83卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

CRYSTAL-STRUCTURE; COMPLEXES; PRECURSORS; LIGAND; CVD;

D O I：

10.1134/S1070363213100204

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The methods of synthesis of the copper(II) beta-diketonates, beta-ketiminates, and beta-diiminates containing in the composition CH3, CF3, C(CH3)(3), and Ph substituents were summarized. At the formation of metallocycles with 2,2,6,6-tetramethyl-3-methylaminoheptane-5-one ligand the intraligand repulsion of tret-butyl group and the methyl group at the nitrogen atom is noted, impeding the complexation.

引用

页码：1919 / 1927

页数：9

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