(Hexamethylbenzene)Ru catalysts for the Aldehyde-Water Shift reaction

被引：18

作者：

Phearman, Alexander S. ^{[1
,2
]}

Moore, Jewelianna M. ^{[1
]}

Bhagwandin, Dayanni D. ^{[2
,3
]}

Goldberg, Jonathan M. ^{[2
]}

Heinekey, D. Michael ^{[2
]}

Goldberg, Karen I. ^{[1
,2
]}

机构：

[1] Univ Penn, Dept Chem, 231 South 34th St, Philadelphia, PA 19104 USA

[2] Univ Washington, Dept Chem, Box 351700, Seattle, WA 98195 USA

[3] CUNY Hunter Coll, Dept Chem, 695 Pk Ave, New York, NY 10065 USA

来源：

GREEN CHEMISTRY | 2021年 / 23卷 / 04期

基金：

美国国家科学基金会;

关键词：

DISPROPORTIONATION; ACETALDEHYDE;

D O I：

10.1039/d0gc03809a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Aldehyde-Water Shift (AWS) reaction uses H2O as a benign oxidant to convert aldehydes to carboxylic acids, producing H-2, a valuable reagent and fuel, as its sole byproduct. (Hexamethylbenzene)Ru-II complexes are demonstrated to have higher activity and selectivity (up to 95%) for AWS over disproportionation than previously reported catalysts.

引用

页码：1609 / 1615

页数：7

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