Decarboxylative Fluorination of Arylcarboxylic Acids Promoted by ortho-Hydroxy and Amino Groups

被引：23

作者：

Wang, Dinghai ^{[1
]}

Yuan, Zheliang ^{[1
]}

Liu, Qilun ^{[1
]}

Chen, Pinhong ^{[1
]}

Liu, Guosheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Univ Chinese Acad Sci, State Key Lab Organometall Chem,Ctr Excellence Mo, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2018年 / 36卷 / 06期

基金：

中国国家自然科学基金;

关键词：

metal-free; decarboxylative; fluorination; aryl carboxylic acids; COPPER-MEDIATED FLUORINATION; CATALYZED FLUORINATION; KINETIC CHARACTERISTICS; AROYLOXYL RADICALS; CARBOXYLIC-ACIDS; CHEMISTRY; PALLADIUM; AMINOFLUORINATION; EXPANSION; FLUORIDE;

D O I：

10.1002/cjoc.201800016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel decarboxylative fluorination process has been developed for the synthesis of ortho-hydroxy/amino arylfluorides from salicylic acid analogs, in which the ortho-hydroxy/amino group plays an important role in the transformation. In addition, various arylfluorides are obtained in good to excellent yields under mild conditions.

引用

页码：507 / 514

页数：8

共 39 条

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